16.11 Rules of the Diels–Alder Reaction
16.11 Rules of the Diels–Alder Reaction
Apr 1, 2015
libretexts.org
Step 2: Researchers have found that changing the substituents on the diene and the dienophile can speed up the reaction and increase yields. Let's first consider the diene characteristics in a Diels-Alder reaction. Two factors affect whether a diene is a good substrate for a Diels-Alder reaction. 1. The conjugated diene must be in the s-cis conformation. 2. Electron-withdrawing groups reduce nucleophilicity. Select the dienes that are not good Diels-Alder substrates. - CHO - OMe
Step 2: Researchers have found that changing the substituents on the …
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